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Journal Articles

Journal Articles

An Improvement in Isotopic Ratio Measurement of Uranium

; ; ;

Shitsuryo Bunseki, 18(4), p.1270 - 1274, 1970/00

no abstracts in English

Oral presentation

Technology and development for nuclear forensics; Result of ITWG collaborative materials exercise

Okubo, Ayako; Shinohara, Nobuo; Toda, Nobufumi; Kataoka, Osamu; Matsumoto, Tetsuya

no journal, , 

no abstracts in English

Oral presentation

The Determination of uranium ratios in individual environmental particles

Tomita, Ryohei; Esaka, Fumitaka; Miyamoto, Yutaka

no journal, , 

In the previous study, we developed a combination method of particle manipulation and secondary ion mass spectrometry (SIMS) for removing the interferences from other elements in other particles. Since the particles were selected randomly and manipulated, it caused the problem not to cover the range of $$^{235}$$U/$$^{238}$$U isotope ratio in the sample. In this study, we improved the procedure of analyzing uranium isotope ratios in individual particles by SIMS to cover the range of $$^{235}$$U/$$^{238}$$U in the sample.

Oral presentation

Development of the uranium isotope ratio analysis for a single uranium particle by MC-ICP-MS using synthetic uranium particles

Tomita, Jumpei; Tomita, Ryohei; Suzuki, Daisuke; Yasuda, Kenichiro; Miyamoto, Yutaka

no journal, , 

The impact of the uranium from the process blank for a single uranium particle analysis by MC-ICP-MS was evaluated quantitatively. The synthetic uranium particles prepared by impregnating of U (NBL CRM U100) to porous silica were used in this study. A conical-bottom bottle was used to dissolve a uranium particle with a small amount of acid. The amount of $$^{238}$$U and $$^{235}$$U/$$^{238}$$U of the process blank were 0.2 pg and 0.0190, respectively. This ratio was similar to that of CRM U015 (0.0155), which was used for the detector calibration of MC-ICP-MS, indicating that the process blank was derived from ultra-trace level of uranium remining in the desolvator. The analytical results indicated that the $$^{235}$$U/$$^{238}$$U ratio could be determined accurately by MC-ICP-MS when the particle contained more than 23 pg of U.

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